Sergey V. Kolotilov Doctor of chemical sciences

Sergey V. Kolotilov

Sergey V. Kolotilov

Doctor of chemical sciences

Head of Department

Telephone: +38 (044) 525 66 61
Fax: +38(044) 525 62 16
Email: s.v.kolotilov@gmail.com

Scope of scientific interests
sorption and catalytic properties of porous coordination polymers of 3d and 4f metals, composites based on porous materials and oxide or metal nanoparticles, multifunctional materials.

Professional experience

2016 – present: Head of Center for collective use of scientific equipment of NAS of Ukraine “Porosity and structure of nanomaterials" (located in L.V.Pisarzhevskii Institute of Physical Chemistry)

2015 – present: Head of Department of porous compounds and materials, L.V.Pisarzhevskii Institute of Physical Chemistry.

2013 – 2015: Leading Research Scientist, L.V.Pisarzhevskii Institute of Physical Chemistry.

2012: Defended the Habilitation thesis entitled “The influence of chemical and crystal structure on magnetic and sorption properties of microporous multispin systems based on polynuclear complexes of 3d metal ions and their nanosized oxides" (advisor: Prof. Vitaly V. Pavlishchuk).
2007 – 2013: Head of the Council of young scientists of L.V.Pisarzhevskii Institute of Physical Chemistry.

2006 – 2013: Senior Research Scientist, L.V.Pisarzhevskii Institute of Physical Chemistry.

2003 – 2006: Research Scientist, L.V.Pisarzhevskii Institute of Physical Chemistry.

Sep. 200 – Dec. 2002: Junior Research Scientist, L.V.Pisarzhevskii Institute of Physical Chemistry.

2002: Defended the Ph.D. thesis entitled “Synthesis, structure, spectral, magnetochemical and redox-properties of polynuclear nickel(II) complexes with oxime-containing ligands" (advisor: Prof. Vitaly V. Pavlishchuk).

Education
1999 – 2002: Post-graduate student at the Department of Physical chemistry of coordination compounds of the Pisarzhevskii Institute (advisor: Prof. Vitaly V. Pavlishchuk).

1994-1999: M.S. in Chemistry, Kiev Taras Shevchenko University (Honors Diploma).

Publications
co-author of more than 80 papers, more than 10 patents of Ukraine

Teaching:
2010 – 2016: Associate professor of the Chair of supramolecular chemistry and biochemistry of the Institute of High technologies at Kiev Taras Shevchenko University.
1999 – 2009: Assistant instructor of the Chair of inorganic chemistry, Chemical Department, Kiev Taras Shevchenko University.
Supervisor of 2 defended PhD thesis. Currently supervisor of 4 PhD students.

Awards
2017: Medal of the State Fund for Fundamental Research of Ukraine “For Contrbution to Science" (2017)

2012: Prize of the President of Ukraine for young scientists (for a work “Coordination compounds with spin crossover and polynuclear exchange clusters as a basis for creation of new materials with different functional properties"; co-author Dr. M. Seredyuk).

2010: Prize of the Parliament of Ukraine for the most gifted young scientists in the field of fundamental and applied research and technical development (for a work “New multi-spin polynuclear complexes as the basis for creation of magnetic materials and nanosized sorbents of different functional destination"; co-author Dr. K. Gavrilenko)

2007: Medal of the National Academy of sciences of Ukraine “Talent, Inspiration, Work".

2004: Prize of the National Academy of sciences of Ukraine for best scientific work for young scientists.

1998: The First prize on Student’s All-Ukrainian Chemistry Olympiad (Kharkov, Ukraine).

1994: Bronze medal on International Chemistry Olympiad (Oslo, Norway).

1994: The Second prize on Chemistry Olympiad of CIS states (Moscow, Russia).

Scientific collaboration
Equipe Organométalliques Matériaux et Catalyse, Institut des Sciences Chimiques de Rennes, Prof. Dr. L. Ouahab

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Dr. Hab. M.A.Kiskin.

Department of Chemistry, Drexel University, Philadelphia, PA 19104-2816, U.S.A., Prof. A. Addison

Selected papers

Pavlishchuk V. V., Kolotilov S. V., Addison A. W., Prushan M. J., Butcher R. J., Thompson L. K. Mono- and Trinuclear Nickel(II) Complexes with Sulfur-Containing Oxime Ligands: Uncommon Templated Coupling of Oxime with Nitrile Inorg. Chem., 1999, 38, 1759-1766.

Pavlishchuk, V. V.; Kolotilov, S. V.; Addison, A. W.; Prushan, M. J.; Schollmeyer, D.; Thompson, L. K.; Goreshnik, E. A. Synthesis, crystal and molecular structures, magnetic, spectral and redox properties of antiferro/ferromagnetic tetranuclear nickel(II) complexes. Angew. Chem., Int. Ed. Engl., 2001, 40, 4734-4737.

Pavlishchuk, V. V.; Kolotilov, S. V.; Addison, A. W.; Prushan, M. J.; Butcher, R. J., Thompson, L. K. A new class of macrocyclic complexes formed via nickel-promoted macrocyclisation of dioxime with dinitrile. Chem. Commun., 2002, 468-469.

Pavlishchuk, V. V.; Kolotilov, S. V.; Addison, A. W.; Prushan, M. J.; Schollmeyer, D.; Thompson, L. K.; Weyhermüller, T.; Goreshnik, E. A. Structural, magnetic and related attributes of some oximate-bridged tetranuclear nickel(II) rhombs and a dinuclear congener J. Chem. Soc., Dalton Trans. 2003, 1588-95.

S.V. Kolotilov, A. W. Addison , S. Trofimenko, W. Dougherty, V. V. Pavlishchuk Efficient mechanochemical synthesis of tris(pyrazolylborate) complexes of manganese(II), cobalt(II) and nickel(II) Inorg. Chem. Commun. 2004, 7, 485-488.

S. V. Kolotilov, O. Shvets, O. Cador, N. Kasian, V. G. Pavlov, L. Ouahab, V. G. Ilyin, V. V. Pavlishchuk Synthesis, structure and magnetic properties of porous magnetic composite, based on MCM-41 molecular sieve with Fe3O4 nanoparticles J. Solid State Chem. 2006, 179, 2426-2432

S. V. Kolotilov, O. Cador, S. Golhen, O. Shvets, V. G. Ilyin, V. V. Pavlishchuk, L. Ouahab Synthesis, structure, sorption and magnetic properties of Ni(II) and Cu(II) complexes with thiosemicarbazone of 2-hydroxybenzaldehyde, bridged by 4,4′-bipyridine Inorg. Chim. Acta 2007, 360, 1883-1889.

A. S. Lytvynenko, S. V. Kolotilov, O. Cador, K. S. Gavrilenko, S. Golhen, L. Ouahab, V. V. Pavlishchuk Porous 2D coordination polymeric formate built up by Mn(II) linking of Fe3O units: influence of guest molecules on magnetic properties
Dalton Trans. 2009, 3503–3509

S. V. Kolotilov, O. Cador, P. Pointillart, S. Golhen, Y. Le Gal, K. S. Gavrilenko, L. Ouahab A new approach towards ferromagnetic conducting materials based on TTF-containing polynuclear complexes J. Mater. Chem., 2010, 9505–9514.

A. V. Pavlishchuk, S. V. Kolotilov, M. Zeller, L. K. Thompson, I. O. Fritsky, A. W. Addison, A. D. Hunter A triple-decker heptadecanuclear (CuII)15(CrIII)2 complex assembled from pentanuclear metallacrowns Eur. J. Inorg. Chem., 2010, 4851–4858.

R. A. Polunin, S. V. Kolotilov, M. A. Kiskin, O. Cador, E. A. Mikhalyova, A. S. Lytvynenko, S. Golhen, L. Ouahab, V. I. Ovcharenko, I. L. Eremenko, V. M. Novotortsev, V. V. Pavlishchuk Topology Control of Porous Coordination Polymers by Building Block Symmetry, Eur. J. Inorg. Chem., 2010, 5055–5057.

A. V. Pavlishchuk, S. V. Kolotilov, M. Zeller, O. V. Shvets, I. O. Fritsky, S. E. Lofland, A. W. Addison, A. D. Hunter Magnetic and Sorption Properties of Supramolecular Systems Based on Pentanuclear Copper(II) 12-Metallacrown-4 Complexes and Isomeric Phthalates: Structural Modeling of the Different Stages of Alcohol Absorption Eur. J. Inorg. Chem., 2011, 4826–4836.

R. A. Polunin, S. V. Kolotilov, M. A. Kiskin, O. Cador, S. Golhen, O. V. Shvets, L. Ouahab, Z. V. Dobrokhotova, V. I. Ovcharenko, I. L. Eremenko, V. M. Novotortsev, V. V. Pavlishchuk Structural flexibility and sorption properties of 2D porous coordination polymers constructed from trinuclear heterometallic pivalates and 4,4′-bipyridine Eur. J. Inorg. Chem., 2011, 4985–4992.

V. N. Dorofeeva, S. V. Kolotilov, M. A. Kiskin, R. A. Polunin, Z. V. Dobrokhotova, O. Cador, S. Golhen, L. Ouahab, I. L. Eremenko, V. M. Novotortsev 2D Porous Honeycomb Polymers versus Discrete Nanocubes from Trigonal Trinuclear Complexes and Ligands with Variable Topology Chem. Eur. J., 2012, 18, 5006 – 5012.

A. V. Pavlishchuk, S. V. Kolotilov, M. Zeller, L. K. Thompson, A. W. Addison Formation of Coordination Polymers or Discrete Adducts via Reactions of Gadolinium(III)-Copper(II) 15-Metallacrown-5 Complexes with Polycarboxylates: Synthesis, Structures and Magnetic Properties, Inorg. Chem., 2014, 53, 1320–1330.

A. S. Lytvynenko, S. V. Kolotilov, M. A. Kiskin, O. Cador, S. Golhen, G. G. Aleksandrov, A. M. Mishura, V. E. Titov, L. Ouahab, I. L. Eremenko, V. M. Novotortsev Redox-Active porous coordination polymers prepared by trinuclear heterometallic pivalate linking with the redox-Active nickel(II) complex: synthesis, structure, magnetic and redox Properties, and electrocatalytic activity in organic compound dehalogenation in heterogeneous medium, Inorg. Chem., 2014, 53, 4970–4979

S. A. Sotnik, R. A. Polunin, M. A. Kiskin, A. M. Kirillov, V. N. Dorofeeva, K. S. Gavrilenko, I. L. Eremenko, V. M. Novotortsev, S. V. Kolotilov, Heterometallic Coordination Polymers Assembled from Trigonal Trinuclear Fe2Ni-Pivalate Blocks and Polypyridine Spacers: Topological Diversity, Sorption, and Catalytic Properties, Inorg. Chem., 2015, 54, 5169–5181

R. A. Polunin, N. P. Burkovskaya, J. A. Satska, S. V. Kolotilov, M. A. Kiskin, G. G. Aleksandrov, O. Cador, L. Ouahab, I. L. Eremenko, V. V. Pavlishchuk, Solvent-Induced Change of Electronic Spectra and Magnetic Susceptibility of CoII Coordination Polymer with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine, Inorg. Chem., 2015, 54, 5232–5238


Notice: ob_end_flush(): failed to send buffer of zlib output compression (0) in /home/inphyschemnaski/public_html/wp-includes/functions.php on line 5275