Pavlo I. Kyriienko   Candidate of Chemical Sciences, Senior Research Scientist   Department of Catalytic Oxidative-Reductive Processes   Ukraine, 03028 Кyiv, prosp. Nauky, 31   Telephone: 38 (044)525-62-22, 38 (050) 573-00-09   E-mail: pavlo_kyriienko@ukr.net

Research interests

• – New processes for obtaining valuable chemical products from renewable raw materials /tandem processes for obtaining 1,3-butadiene and 2-ethylhexanol, etc./ from C2, 4– bioalcohols;
• – Catalytic and plasma-catalytic conversion of CO2 and biogas into valuable chemicals;
• – Oxidative dehydrogenation of light hydrocarbons;
• – Structural and functional design of the catalysts for neutralization of technogenic gas exhausts of stationary and mobile sources from NOx, CO and volatile organic compounds.

Professional experience

Scientific and organizational activities

Education

• – National Technical University of Ukraine “Kyiv Polytechnic Institute”, Chemical Technology of Inorganic Substances Faculty (2007);
• – Postgraduate study with a break from production (Chemical Kinetics and Catalysis) at L.V. Pisarzhevskii Institute of Physical Chemistry of NASU (2010);
• – Candidate of Chemical Sciences (Ph.D.) in the specialty 02.00.15 – Chemical Kinetics and Catalysis, Ph.D. thesis “Effect of the composition of metal-oxide catalysts Pd(Pt)–MxOy/cordierite (M: Co, Cu) on their activity in CO, NO, O2, hexane redox reactions”, supervisor – Doctor of Chemical Sciences, Prof. S.O. Soloviev (2011).

Scholarships and Scientific awards

• – Scholarship of the President of Ukraine for Young Scientists (2010–2012);
• – Scholarship named after L.V. Pisarzhevskii for Young Scientists (2013);
• – The Prize of the President of Ukraine for Young Scientists “Development of new generation nanostructured catalysts for industrial processes and environmental protection” (together with I.V. Gubareni and N.O. Popovych, 2015);
• – The Prize of the National Academy of Sciences of Ukraine for Young Scientists “Talent, Inspiration, Work” (2017).

Grants

– Grant of the National Academy of Sciences of Ukraine for implementation of the research project of young scientists of NASU “Development of structured catalysts for selective reduction of NOx with oxygenates and oxidative conversion of C1-C4 alkanes” (manager, 2011–2012);

• – Grant of the President of Ukraine for implementation of the research project of young scientists “Development of effective catalysts for the processes of selective reduction of nitrogen oxides with oxygenates and oxidative conversion of natural gas to obtain synthesis gas with controlled composition” (manager, 2013);
• – Grant of the National Academy of Sciences of Ukraine to a research group of young scientists of NASU for research in priority areas of science and technology “Nanostructured catalysts for obtaining of valuable organic compounds via chemical and plasma-chemical activation of CO2 and renewable raw materials” (2018–2019);
• – Grants of the Central European Research Infrastructure Consortium (CERIC) for research at Charles University (Prague, Czech Republic, 2017, 2019) and the National Institute of Chemistry (Ljubljana, Slovenia, 2019).

Scientific cooperation

• – Prof. Stanislaw Dzwigaj, Laboratoire de Réactivité de Surface, Sorbonne Université-CNRS, Paris, France;
• – Ph.D. D.Yu. Balakin, Ph.D. V.V. Tsiolko, Institute of Physics of NASU, Department of Adsorption Phenomena;
• – Ph.D. V.I. Kornaga, V.Ye. Lashkaryov Institute of Semiconductor Physics of NASU, Department of Optoelectronics;
• – Ph.D. Mykhailo Vorokhta, Ph.D. Ivan Khalakhan, Charles University, Department of Surface and Plasma Sciences, Prague, Czech Republic;
• – Ph.D. S.A. Sergiienko, University of Aveiro, CICECO-Aveiro Institute of Materials, Department of Materials and Ceramics Engineering, Aveiro, Portugal.

Total number of publications: chapters in collective English monographs – 4, articles – 52, patents – 11.

Identification codes in scientometric databases: Scopus – 55314336200, ResearcherID – L-9383-2017, ORCID – 0000-0003-1533-3492.

List of selected publications

1. Kyriienko, P.I.; Larina, O.V.; Balakin, D.Y.; Stetsuk, A.O.; Nychiporuk, Y.M.; Soloviev, S.O.; Orlyk, S.M. 1,3-Butadiene Production from Aqueous Ethanol over ZnO/MgO-SiO2 Catalysts: Insight into H2O Effect on Catalytic Performance. Appl. Catal. A Gen. 2021, 616, 118081. https://doi.org/10.1016/j.apcata.2021.118081

2. Kyriienko, P.I.; Larina, O.V.; Soloviev, S.O.; Orlyk, S.M. Catalytic Conversion of Ethanol Into 1,3-Butadiene: Achievements and Prospects: A Review. Theor. Exp. Chem. 2020, 56 (4), 213–242. https://doi.org/10.1007/s11237-020-09654-2

3. Kyriienko, P.I. Selective Catalytic Reduction of NOx with Ethanol and Other C1-4 Oxygenates over Ag/Al2O3 Catalysts: A Review. Front. Chem. Sci. Eng. 2020, 14 (4), 471–491. https://doi.org/10.1007/s11705-019-1847-7

4. Larina, O.V.; Shcherban, N.D.; Kyriienko, P.I.; Remezovskyi, I.M.; Yaremov, P.S.; Khalakhan, I.; Mali, G.; Soloviev, S.O.; Orlyk, S.M.; Dzwigaj, S. Design of Effective Catalysts Based on ZnLaZrSi Oxide Systems for Obtaining 1,3-Butadiene from Aqueous Ethanol. ACS Sustain. Chem. Eng. 2020, 8 (44), 16600–16611. https://doi.org/10.1021/acssuschemeng.0c05925 

5. Larina, O.V; Remezovskyi, I.M.; Kyriienko, P.I.; Soloviev, S.O.; Orlyk, S.M. 1,3-Butadiene Production from Ethanol–Water Mixtures over Zn–La–Zr–Si Oxide Catalyst. React. Kinet. Mech. Catal. 2019, 127 (2), 903–915. https://doi.org/10.1007/s11144-019-01618-5

6. Soloviev, S.O.; Kyriienko, P.I.; Popovych, N.O.; Larina, O.V. Development of Catalysts for Abating Toxic Nitrogen Oxides in Gas Emissions of Nitrogen Acid Production. Sci. Innov. 2019, 15 (1), 59–71. http://scinn-eng.org.ua/archive/15(1)/15(1)04 

7. Larina, O.V.; Kyriienko, P.I.; Balakin, D.Y.; Vorokhta, M.; Khalakhan, I.; Nychiporuk, Y.M.; Matolín, V.; Soloviev, S.O.; Orlyk, S.M. The Effect of ZnO on Acid-Base Properties and Catalytic Performance of ZnO/ZrO2-SiO2 Catalysts in 1,3-Butadiene Production from Ethanol-Water Mixture. Catal. Sci. Technol. 2019, 9, 3964–3978. https://doi.org/10.1039/C9CY00991D.

8. Larina, O.V; Valihura, K.V; Kyriienko, P.I.; Vlasenko, N.V; Balakin, D.Y.; Khalakhan, I.; Čendak, T.; Soloviev, S.O.; Orlyk, S.M. Successive Vapour Phase Guerbet Condensation of Ethanol and 1-Butanol over Mg-Al Oxide Catalysts in a Flow Reactor. Appl. Catal. A Gen. 2019, 588, 117265. https://doi.org/10.1016/j.apcata.2019.117265

9. Popovych, N.O.; Kyriienko, P.I.; Millot, Y.; Valentin, L.; Gurgul, J.; Socha, R.P.; Żukrowski, J.; Soloviev, S.O.; Dzwigaj, S. Sn-BEA Zeolites Prepared by Two-Step Postsynthesis Method: Physicochemical Properties and Catalytic Activity in Processes Based on MPV Reduction. Microporous Mesoporous Mater. 2018, 268, 178–188. ttps://doi.org/10.1016/j.micromeso.2018.04.026

10. Kurmach, M.M.; Larina, O.V.; Kyriienko, P.I.; Yaremov, P.S.; Trachevsky, V.V.; Shvets, O.V.; Soloviev, S.O. Hierarchical Zr-MTW Zeolites Doped with Copper as Catalysts of Ethanol Conversion into 1,3-Butadiene. Chemistry Select 2018, 3 (29), 8539–8546. https://doi.org/10.1002/slct.201801971.

11. Kyriienko, P.I.; Larina, O.V.; Soloviev, S.O.; Orlyk, S.M.; Calers, C.; Dzwigaj, S. Ethanol Conversion into 1,3-Butadiene by the Lebedev Method over MTaSiBEA Zeolites (M = Ag, Cu, Zn). ACS Sustain. Chem. Eng. 2017, 5 (3), 2075–2083. https://doi.org/10.1021/acssuschemeng.6b01728