Teoret. i eksperim. khimiya. 2004. Vol.40 No. 1. p. 7-11 — Інститут фізичної хімії ім. Л.В.Писаржевського НАНУ

Sensitization of Photoconductivity of the Polymeric Compositions

with Nanoparticles of Fe2O3 and CdS by Organic Compound

with Intramolecular Charge Transfer

Yu. P. Getmanchuk, I. I. Davidenko, N. A. Davidenko,

E. V. Mokrinskaya, D. D. Mysyk*, R. D. Mysyk*

Kyiv Taras Shevchenko National University

64 Volodymyrska Vul., 01033 Kyiv, Ukraine. Е-mail: daviden@ukrpack.net

* Donetsk National Technical University

58 Artema Vul., 83000 Donetsk, Ukraine. Е-mail: romanmysyk@yahoo.com

Electric and photoconductivity of the films based on polyvinylbutyral containing nanoparticles of Fe2O3 and CdS and organic compounds with intramolecular charge transfer as sensitizers of the photoconductivity in visible and near IR parts of spectrum are investigated. Within adsorbtion range of the sensitizer, the activation energy of the photocurent slightly exceeds 0.1 eV and it is close to the activa- tion energy of electric conductivity.

Key words: polymeric compositions, nanoparticles, organic compounds with intramolecular charge transfer, electric

conductivity, photoconductivity.

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