Gavrish Sergey Pavlovich candidate of chemical sciences (PhD)

Gavrish Sergey Pavlovich

Gavrish Sergey Pavlovich

candidate of chemical sciences (PhD), research scientist

department of physical inorganic chemistry

Ukraine, 03039, Kyiv-39, prospect Nauki, 31
tel.: +38 (044) 525-25-70;
Email: gavrish_sp@ukr.net

Scientific interests
Synthesis and investigation of the structure and properties of the transition metal (copper, nickel, zinc, palladium) complexes with polychelate and macrocyclic tetraaza ligands and based on them coordination polymers by means of X-ray diffraction analysis, spectroscopy (NMR, IR, electronic), electrochemical and adsorption methods.

 

Professional experience

1984–1986 Special student-scientist
1986–1993 Engineer
1993–1994 Junior Research Scientist
1994– till present Research Scientist

 

Education

– Moscow Institute of Physics and Technology, Department of Molecular and Chemical Physics (1984)

– Candidate of Sciences (PhD) (1993).

 

Publications – more than 50, in particular 34 scientific papers.
Identification codes in scientific data bases: ORCID – 0000-0002-6482-8224.

 

Selected publications

1. Gavrish, S. P.; Shova, S.; Cazacu, M.; Lampeka, Ya. D. Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]2+ cation and the dianion of diphenylsilanediylbis(4-benzoic acid). Acta Cryst. Sect. E 2020, 76(6), 929–932. https://dx.doi.org/10.1107/S2056989020006544

2. Gavrish, S. P.; Shova, S.; Cazacu, M.; Dascalu, M.; Lampeka, Ya. D Syntheses and crystal structures of the one-dimensional coordination polymers formed by [Ni(cyclam)]2+ cations and 1,3-bis(3-carboxypropyl)tetramethyldisiloxane anions in different degrees of deprotonation. Acta Cryst. Sect. E 2020, 76(3), 446–451. https://dx.doi.org/10.1107/S2056989020002327

3. Gavrish, S. P.; Shova, S.; Cazacu, M.; Lampeka, Ya. D. A 2D coordination polymer assembled from a nickel(II) tetraazamacrocyclic cation and 4,4-(dimethylsilanediyl)diphthalate(3-) linker. Acta Cryst. Sect. C 2020, 76(5), 419–426. https://dx.doi.org/10.1107/S2053229620005008

4. Gavrish, S. P.; Lampeka, Ya. D.; Babak, M. V.; Arion, V. B. Palladium Complexes of N,N-Bis(2-aminoethyl)oxamide (H2L): Structural (PdIIL, PdII2L2, and PdIVLCl2), Electrochemical, Dynamic 1H NMR and Cytotoxicity Studies. Inorg. Chem. 2018, 57(3), 1288–1297. https://dx.doi.org/10.1021/acs.inorgchem.7b02732

5. Gavrish, S. P.; Lampeka, Ya. D.; Lightfoot, P. Metal-dependent structural variations and the peculiarities of hydrogen-bonded networks in the highly hydrated copper(II), nickel(II), and palladium(II) complexes of bis-dioxocyclam. Cryst. Growth Des. 2015, 15(4), 2024–2032. https://dx.doi.org/10.1021/acs.cgd.5b00217

6. Gavrish, S. P. Approximate expressions and the relationship between pyramidalization (out-of-plane deformation) characteristics of trigonal centers. J. Comput. Chem. 2012, 33(27), 2173–2179. https://dx.doi.org/10.1002/jcc.23053

7. Gavrish, S. P.; Lampeka, Ya. D.; Lightfoot, P.; Arion, V. B.; Keppler, B. K.; Woźniak, K. Solid state structural variations in copper(II) complexes of open-chain and macrocyclic malonamide-derived ligands. Cryst. Growth Des. 2012, 12(9), 4388–4396. https://dx.doi.org/10.1021/cg300554r

8. Gavrish, S. P.; Lampeka, Ya. D.; Pritzkow, H.; Lightfoot, P. Syntheses, solid state and solution structures of the palladium(II) complexes of malonamide-derived open-chain and macrocyclic ligands. Dalton Trans. 2010, 39(33), 7706–7713. https://dx.doi.org/10.1039/c0dt00376j

9. Gavrish, S. P.; Lampeka, Ya. D.; Lightfoot, P.; Pritzkow, H. Crystal and molecular structures of related nickel(II) complexes of open-chain and macrocyclic oxamide based ligands and the peculiarities of water aggregates in their crystal lattices. Dalton Trans. 2007, 41, 4708–4714. https://dx.doi.org/10.1039/b708006a

10. Gavrish, S. P.; Lampeka, Ya. D.; Lightfoot, P. Solution properties of the nickel(II,III) and copper(II,III) complexes of trans-dioxocyclam (trans-dioxocyclam = 5,12-dioxo-1,4,8,11-tetraazacyclo-tetradecane) and the X-ray crystal structure of the N-rac isomer of the nickel(II) complex. Inorg. Chim. Acta 2004, 357(4), 1023–1030. https://dx.doi.org/10.1016/j.ica.2003.09.035

11. Hansen, L.; Lampeka, Ya. D.; Gavrish, S. P.; Xu, X.; Taylor, A. T.; Marzilli, L. G. Re(V) complexes with an open-chain quadridentate ligand containing two amine and two amido donors. Synthesis, characterization, and solution equilibria of Re2O3(dioxo-tetH4)2 and [ReO(H2O)(dioxo-tetH4)]Cl (dioxo-tetH6 = 1,4,8,11-tetraazaundecane-5,7-dione). Inorg. Chem. 2000, 39(25), 5859–5866. https://dx.doi.org/10.1021/ic000173p

12. Lampeka, Ya. D.; Gavrish, S. P. Spectral characteristics of the copper(III) and nickel(III) coordination compounds with open-chain and macrocyclic dioxotetraamines. Polyhedron 2000, 19(26–27), 2533–2538. https://dx.doi.org/10.1016/S0277-5387(00)00557-X

13. Lampeka, Ya. D.; Gavrish, S. P.; Hay, R. W.; Eisenblatter, T.; Lightfoot, P. The crystal and molecular structures of the nickel(II) complexes of malonamide-derived unsubstituted 14- and 13-membered tetraaza macrocycles and NMR study of the complexes in aqueous solution. J. Chem. Soc., Dalton Trans. 2000, 13, 2023–2029. https://dx.doi.org/10.1039/b001510p


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