Lampeka Yaroslaw D.

Doctor hab., Professor in Inorganic Chemistry,

Corresponding Member of the National Academy of Sciences of Ukraine

Ukraine, 03039, Kyiv-39, prospect Nauki, 31
Phone:  +38 (044) 525-65-40
Email: lampeka@adamant.net

Scientific interests

Synthesis, spectral and redox properties of transition metal complexes with polydentate (including azamacrocyclic) ligands, structure of coordination compounds is solution and in crystalline state, study of kinetic features and mechanisms of redox reactions of coordination compounds; metal-organic frameworks and composites based thereon, their adsorption, catalytic and redox properties; supramolecular chemistry, host-guest interactions

Professional experience

Scientific-organizational activity
– The member of academic council of IPhCh (since 2012)
– Scientific secretary of specialized academic council D 26.190.01 in IPhCh (since 2004)
– The member of specialized academic council D 26.001.03 in Taras Shevchenko Kyiv National University (since 2013)
– The member of working groups of special-purpose complex programs of fundamental research of the National Academy of Sciences of Ukraine “Fundamental problems of creation of new substances and materials of chemical production” (2012-2016) and “New functional substances and materials of chemical production” (2017-2021)
– The member of expert board in chemical sciences of Higher Attestation Commission of Ukraine (2005-2010)

Education

Chemistry Department of Taras Shevchenko Kyiv State University (1976)
Post-graduate student (inorganic chemistry) IPhCh (1979)
Candidate of Chemical Sciences (1980)
Doctor of Chemical Sciences (Dr. hab.) (1999)
Professor (2002)
Corresponding Member of the National Academy of Sciences of Ukraine (2021)

Awards, prizes and other achievements

– The Deed of Supreme Council of Ukraine for merits to Ukrainian people (2017)
– The State Award of Ukraine in Area of Science and Technology (1991)
– L.V. Pisarzhevskii Award of the National Academy of Sciences of Ukraine (1997)
– O.I.Brodski Award of the National Academy of Sciences of Ukraine (1997)
– Distinction of the National Academy of Sciences of Ukraine for training of scientific young generation (2007)
– Distinction of the National Academy of Sciences of Ukraine for scientific achievements (2014)
– Distinction of the National Academy of Sciences of Ukraine for 100-years of the National Academy of Sciences of Ukraine (2018)

General characteristics of the publications
Загальна кількість публікацій – 281, в т.ч.
Total number of publication – 281, including
– Monograph – 1
– Scientific papers – 161
– Patents – 4
ORCID ID code – 0000-0003-3800-6697

Scientific cooperation
Professor V. Arion, Institute of Inorganic Chemistry, University of Vienna (Austria)
Doctor S. Shova, “Petru Poni Institute of Macrovolecular Chemistry, Romania
Professor Р. Comba, Anorganisch-Chemisches Institut, University of Heidelberg (Germany)
Professor Ph. Lightfoot, School of Chemistry, University of St. Andrews (UK)

List of selected publications

1. Tsymbal L.V., Rodik R.V., Danylyuk O., Suwinska K., Lipkowski J., Kalchenko V. I., Lampeka Ya. D. Supramolecular interactions in the heteroarylimine-substituted calix[4]arenes: the formation of cyclic dodecanuclear palladium aggregates / Supramol. Chem., 2021 https://dx.doi.org/10.1080/10610278.2021.1944632
2. Tsymbal L.V., Andriichuk I.L., Shova S., Trzybiński D., Woźniak K., Arion V.B., Lampeka Ya D. Coordination polymers of the macrocyclic nickel(II) and copper(II) complexes with isomeric benzenedicarboxylates: the case of spatial complementarity between the bis-macrocyclic complexes and o-phthalate / Cryst. Growth Des., 2021, 21(4), 2355–2370 https://dx.doi.org/10.1021/acs.cgd.1c00011
3. Gavrish S.P., Shova S., Cazacu M., Lampeka Ya. D. A 2D coordination polymer assembled from a nickel(II) tetraazamacrocyclic cation and 4,4′-(dimethylsilanediyl)diphthalate(3-) linker / Acta Crystallogr. Sect. C, 2020, C76(5), 419–426 https://dx.doi.org/10.1107/S2053229620005008
4. Gavrish S. P., Lampeka Ya. D., Babak M. V., Arion V. B. Palladium complexes of N,N-bis(2-aminoethyl)oxamide (H2L): structural (PdIIL, PdII2L2, and PdIVLCl2), electrochemical, dynamic 1H NMR and cytotoxicity studies / Inorg. Chem., 2018, 57(3), 1288–1297 https://dx.doi.org/10.1021/acs.inorgchem.7b02732
5. Lampeka Ya. D., Tsymbal L. V. Preparation, structure and functional properties of MoS2 and WS2 nanocomposites with inorganic chalcogenide semiconductors: a review / Theor. Exper. Chem., 2017, 53(4) 211–234. https://doi.org/10.1007/s11237-017-9519-5
6. Gavrish S.P., Lampeka Ya.D., Lightfoot P. Metal-dependent structural variations and the peculiarities of hydrogen-bonded networks in the highly hydrated copper(II), nickel(II), and palladium(II) complexes of bis-dioxocyclam / Cryst. Growth Des., 2015, 15(4), 2024–2032 https://dx.doi.org/10.1021/acs.cgd.5b00217
7. Lampeka Ya. D., Tsymbal L. V. Nanocomposites of two-dimensional molybdenum and tungsten dichalcogenides with metal particles: preparation and prospects for application / Theor. Exper. Chem., 2015, 51(3), 141–162. https://doi.org/10.1007/s11237-015-9410-1
8. Tsymbal L.V., Lampeka Ya.D., Boyko V.I., Kalchenko V.I., Shishkina S.V., Shishkin O.V. A ladder-type coordination polymer constructed from two macrocyclic units – calix[4]arene tetracarboxylate and azamacrocyclic nickel(II) complex / CrystEngComm., 2014, 16(18), 3707–3711 https://doi.org/10.1039/C3CE42279H
9. Gavrish S.P., Lampeka Ya.D., Lightfoot P., Arion V.B., Keppler B.K., Woźniak K. Solid state structural variations in copper(II) complexes of open-chain and macrocyclic malonamide-derived ligands / Cryst. Growth Des., 2012, 12(9), 4388–4396 https://dx.doi.org/10.1021/cg300554r
10. Lampeka Ya.D., Tsymbal L.V., Barna A.V., Shuĺga Yu.L., Shova S., Arion V.B. Catenation control in the two-dimensional coordination polymers based on tritopic carboxylate linkers and azamacrocyclic nickel(II) complexes / Dalton Trans. 2012, 41(14), 4118–4125 https://dx.doi.org/10.1021/cg300554r
11. Comba, P., Lampeka Ya.D., Prikhod’ko A.I., Rajaraman G. Determination of the solution structures of melamine-based bis- and tris-macrocyclic ligand copper(II) complexes / Inorg. Chem., 2006, 45(9), 3632–3638 https://doi.org/10.1021/ic052124o
12. Atanasov M., Comba P., Lampeka Ya.D., Linti G., Malcherek T., Miletich R., Prikhod’ko A.I., Pritzkow H. Encapsulation of cyanometalates by a tris-macrocyclic ligand tricopper(II) complex: syntheses, structural variation, and magnetic exchange coupling pathways / Chem. Eur. J. 2006, 12(3), 737–748 https://doi.org/10.1002/chem.200500365
13. Comba P., Kerscher M., Lampeka Ya.D., Lötzbeyer L., Pritzkow H., Tsymbal L.V. Structural properties of cyclopentanone-bridged bis-macrocyclic ligand dicopper(II) complexes in the solid and in solution: a successful test of the MM-EPR method / Inorg. Chem., 2003, 42(11), 3387–3389 https://doi.org/10.1021/ic026265r
14. Comba P., Lampeka Ya.D., Lötzbeyer L., Prikhod´ko A.I. Macrocyclic melamine-based ligand complexes as building blocks for the metal-directed synthesis of heterometallic di- and trinuclear compounds / Eur. J. Inorg. Chem., 2003, (1), 34–37 https://doi.org/10.1002/ejic.200390002
15. Lampeka Ya. D., Tsymbal L. V. Framework materials based on azamacrocyclic complexes of transition metals and carboxylates / Theor. Exper. Chem., 2004, 40(6), 345–371. https://doi.org/10.1007/s11237-005-0001-4
16. Yatsimirskii K.B., Lampeka Ya.D. Physico-chemistry of Metal Complexes with Macrocyclic Ligands (Russ.), Naukova Dumka, Kiev, 1985, 256 p.